The crystal structures of a series of mercury(II) chloride complexes R3M,HgCl2 have been found to range from discrete chlorine-bridged dimers (R = Ph, X = As or P) to chain-like arrangements made up of monomeric Et3P,HgCl2 units or [Me3P,HgCl]+Cl–ions.
N. A. Bell, M. Goldstein, T. Jones and I. W. Nowell, J. Chem. Soc., Chem. Commun., 1976, 1039 DOI: 10.1039/C39760001039
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