The rotatory strength, R, of chiral conformers of acetone is proportional (but opposite in sigh) to θ(n)–θ(π*); θ(n) and θ(π*) represent twists of the n and π* orbitals of the oxygen atom of the carbonyl group.
E. E. Ernstbrunner, M. R. Giddings and J. Hudec, J. Chem. Soc., Chem. Commun., 1976, 953 DOI: 10.1039/C39760000953
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