The 13C n.m.r. spectrum of averufin has been completely assigned, providing unambiguous proof of its structure; the 13C n.m.r. spectra of averufin enriched with [1-13C]-, [2-13C]-, and [1,2-13C2]-acetate by Aspergillus parasiticus established its formation from ten intact acetate units and the mode of folding of the precursor decaketide chain.
C. P. Gorst-Allman, K. G. R. Pachler, P. S. Steyn, P. L. Wessels and D. B. Scott, J. Chem. Soc., Chem. Commun., 1976, 916 DOI: 10.1039/C39760000916
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