Issue 21, 1976

Cycloaddition of benzocinnoline N-acylimides to diphenylketen

Abstract

Benzo[c]cinnoline N-acylimides (1) give the rearranged adducts (2) with diphenylketen; the ylide (6) can be intercepted in this reaction suggesting that the expected 1,3-diplor cycloadduct (5) is formed initially and rearranges to (2) both intramolecularly and by dissociation-recombination.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 888-890

Cycloaddition of benzocinnoline N-acylimides to diphenylketen

S. H. Alsop, J. J. Barr, R. C. Storr, A. F. Cameron and A. A. Freer, J. Chem. Soc., Chem. Commun., 1976, 888 DOI: 10.1039/C39760000888

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