Hydrogenation over palladium of certain aromatic and cyclo-olefinic hydrocarbons proceeds with addition of hydrogen from the side of the molecule opposite to the catalyst; this result supports the Rideal mechanism.
M. Farina, C. Morandi, E. Mantica and D. Botta, J. Chem. Soc., Chem. Commun., 1976, 816 DOI: 10.1039/C39760000816
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