The tertiary allylic alcohol (2) is readily dehydrated by catalytic amounts of non-aqueous acid to the cyclopentadiene derivative (3), which is subsequently regiospecifically transformed to the vinyl sulphide (6) by pyrolysis.
R. D. Miller, J. Chem. Soc., Chem. Commun., 1976, 277 DOI: 10.1039/C39760000277
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