Issue 6, 1976

Acetoxythallation of terminal acetylenes

Abstract

The reaction of terminal acetylenes with Tl-(OAc)3 in chloroform gives a new type of oxythallation adduct; this was shown to be one of the intermediates in the thallium(III) salt-catalysed conversion of terminal acetylenes into ketones.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 218-219

Acetoxythallation of terminal acetylenes

S. Uemura, H. Miyoshi, H. Tara, M. Okano and K. Ichikawa, J. Chem. Soc., Chem. Commun., 1976, 218 DOI: 10.1039/C39760000218

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