Issue 5, 1976

Controlling the outcome of a carbonium ion reaction: the use of a trimethylsilyl group to dictate the formation of a specific olefin

Abstract

The carbonium ions (2, R = SiMe3) and (6, R = SiMe3) give only the olefins (4) and (7), respectively, in contrast to the reactions of the carbonium ions (2, R = H) and (6, R = H).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 182-183

Controlling the outcome of a carbonium ion reaction: the use of a trimethylsilyl group to dictate the formation of a specific olefin

I. Fleming, A. Pearce and R. L. Snowden, J. Chem. Soc., Chem. Commun., 1976, 182 DOI: 10.1039/C39760000182

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