The adduct Na(C5H5)(Me2NCH2CH2NMe 2), prepared from Na(C5H5) and an equimolar proportion (or excess) of Me2NCH2CH2NMe2 in THF, adopts a puckered chain structure in the crystal in which Na(Me2NCH2CH2NMe2) units are linked by bridging h5-C5H5 rings.
T. Aoyagi, H. M. M. Shearer, K. Wade and G. Whitehead, J. Chem. Soc., Chem. Commun., 1976, 164 DOI: 10.1039/C39760000164
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