Issue 2, 1976

Absolute configuration at the chiral nitrogen atom in an optically active oxaziridine. X-Ray structure of (2S)-(–)-N-(R)-α-methyl-benzyldiphenyloxaziridine

Abstract

(R)-(–)-(Diphenylmethylene)-α-methylbenzyl-amine reacts with organic peroxy-acids in chloroform solution to give stereospecifically (2S)-(–)-N-(R)-α-methylbenzyldiphenyloxaziridine; X-ray crystal structure analysis shows that the absolute configuration at the configurationally stable chiral nitrogen atom is (S).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 60-61

Absolute configuration at the chiral nitrogen atom in an optically active oxaziridine. X-Ray structure of (2S)-(–)-N-(R)-α-methyl-benzyldiphenyloxaziridine

M. Bucciarelli, I. Moretti, G. Torre, G. D. Andreetti, G. Bocelli and P. Sgarabotto, J. Chem. Soc., Chem. Commun., 1976, 60 DOI: 10.1039/C39760000060

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