Issue 2, 1976

New synthetic route to trialkyloxonium salts: alkylation of ethers with acyldialkyl cations

Abstract

Acylium cations or complexes of acyl halides with nonmetal halides (e.g. PhCO+SbF6 or PhCOClSbCl5) react at low temperature with an excess of alkyl ethers (e.g. Me2O or Et2O) giving the corresponding trialkyloxonium salts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 33-34

New synthetic route to trialkyloxonium salts: alkylation of ethers with acyldialkyl cations

R. Szymański, H. Wieczorek, P. Kubisa and S. Penczek, J. Chem. Soc., Chem. Commun., 1976, 33 DOI: 10.1039/C39760000033

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