Methods for extrapolating rates for nitrations in aqueous sulphuric acid to different temperatures and acidities are discussed. A standard procedure to obtain k0 values at 25° and H0–6.6 is applied to literature data for 131 nitration rates. Allowance is made where necessary for minority species concentrations.
A. R. Katritzky, B. Terem, E. V. Scriven, S. Clementi and H. O. Tarhan, J. Chem. Soc., Perkin Trans. 2, 1975, 1600 DOI: 10.1039/P29750001600
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