Thermolysis or photolysis of sulphamoyl azides does not lead to sulphamoylnitrenes; complex reactions occur, involving mainly S–N bond cleavage and some C–N cleavage. The intramolecular cyclisation of some intermediate sulphamoyl chlorides are described.
R. A. Abramovitch and K. Miyashita, J. Chem. Soc., Perkin Trans. 1, 1975, 2413 DOI: 10.1039/P19750002413
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