The addition of fluorine, by cobalt trifluoride, to the double bonds of 1H,2H-octafluorocyclohexene and 1H,2H hexafluorocyclopentene is not highly stereoselective; cis : trans ratios of about 1 : 7 and 2 : 3.9, respectively, have been obtained.
A. Bergomi and J. Burdon, J. Chem. Soc., Perkin Trans. 1, 1975, 2237 DOI: 10.1039/P19750002237
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