Evidence is presented that photolytic fission of the C–Br bonds of bromobiphenyls is preceded by electron transfer. The enhanced rate of photodecomposition of 2-bromobiphenyls is shown to result from the release of steric strain in the excited state.
N. J. Bunce, S. Safe and L. O. Ruzo, J. Chem. Soc., Perkin Trans. 1, 1975, 1607 DOI: 10.1039/P19750001607
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...