Issue 0, 1975

Quantum-mechanical systems restricted by impenetrable barriers studied by a perturbation method

Abstract

A systematic perturbation method to calculate the explicit dependence of energy on the position of the repulsive barrier (or barriers) in one-dimensional non-degenerate systems is presented. The method is also capable of dealing with anisotropic shifts of the boundaries. Two simple applications illustrate the general principles (particle in a box and compression of the ground state of the hydrogen atom).

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1975,71, 2016-2024

Quantum-mechanical systems restricted by impenetrable barriers studied by a perturbation method

I. Gonda and B. F. Gray, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 2016 DOI: 10.1039/F29757102016

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