Issue 0, 1975

Electron-coupled through-space or fragment spin-spin coupling between 19F nuclei

Abstract

The indirect spin-spin coupling constants over four formal bonds between fluorine nuclei in 2-fluoro-5-nitrobenzotrifluoride, 2,5-difluorobenzotrifluoride, pentafluorobenzoyl fluoride, and 2-fluoro-6-chlorobenzoyl fluoride, are +12.94 ± 0.02, +13.0 ± 0.1, +38.8 ± 0.1, and +30.6 ± 0.1 Hz, respectively. These “through-space” or “fragment” interactions are compared with previous sign and magnitude measurements and are in agreement with two semiempirical theories.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1975,71, 1526-1528

Electron-coupled through-space or fragment spin-spin coupling between 19F nuclei

T. Schaefer, W. Niemczura and K. Marat, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 1526 DOI: 10.1039/F29757101526

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