Ab initio calculations on the low-lying electronic states of C2H have been performed. Its ground and first excited states are found to be X2Σ+ and A2Π respectively. Evidence is given in support of the assignment of the observed 10 000 Å band system to the transition between these states.
S. P. So and W. G. Richards, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 660 DOI: 10.1039/F29757100660
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