The kinetics of the thermolysis of octamethylcyclotetrasiloxane have been studied in the gas phase between 767 and 925 K. A mechanism has been deduced involving the intermediate Me2SiO, and conclusions are drawn about the stability and chemical behaviour of Me2SiO.
I. M. T. Davidson and J. F. Thompson, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 2260 DOI: 10.1039/F19757102260
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