X-Ray crystal and molecular structure determination of a novel bicyclic system. 2-p-Bromophenyl-1,3-diazabicyclo[3,1,0] hexane

Abstract

The crystal and molecular structure as well as the conformation of 2-p-bromophenyl-1,3-diazabicyclo-[3,1,0]hexane C₁₀H₁₁N₂Br, have been determined by X-ray structure analysis; the 1,3-diazabicyclo[3,1,0]-hexane fragment of the molecule has the boat conformation, and the benzene ring orients itself in the exo-position to the heterohexane bicycle.