The results of stereochemical and product studies on the chlorination of phosphorus thionesters are rationalized in terms of phosphonium and five-co-ordinate intermediates which in the case of thionophos-phonates and cyclic five-membered thionophosphates undergo nucleophilic ligand exchange.
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A. Skowrońska, J. Mikolajczak and J. Michalski, J. Chem. Soc., Chem. Commun., 1975, 986 DOI: 10.1039/C39750000986
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