The reaction of an excess of [(2-mercaptoethylamine)-N,S] bis (ethylenediamine)cobalt(III) with the one-equivalent oxidant NpVI(or [Coaq]3+) in aqueous HClO4 gives [(2-aminoethyl 2-ammonioethyl disulphide-N,S]-bis(ethylenediamine)cobalt(III)via induced electron transfer and a presumed radical ion dimer intermediate.
M. Woods, J. C. Sullivan and E. Deutsch, J. Chem. Soc., Chem. Commun., 1975, 749 DOI: 10.1039/C39750000749
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