The reaction of OH radicals with (NH3)5CoIIIpy3+(k= 6·5 × 108M–1 s–1) at pH 5·2 yields Co2+; the OH-adduct to the pyridine ligand, detected by pulse radiolysis, undergoes slow first-order decay (k= 6·0 s–1).
M. Z. Hoffman and D. W. Kimmel, J. Chem. Soc., Chem. Commun., 1975, 549 DOI: 10.1039/C39750000549
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