Issue 12, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

Ring opening of 2,3-bis(hydroxymethyl)methylenecyclopropanes with [Fe2(CO)9]; the molecular structure of a 1,4-diene complex of iron(0), tricarbonyl-η4-(3-methylene-4-vinyldiphydrofuran-2(3H)-one) iron

Michael Green,   Russell P. Hughes  and  Alan J. Welch  

Abstract

trans- or cis-2,3-Bis(hydroxymethyl)methylenecyclopropanes react with [Fe2(CO)9] to yield ring-opened products containing the 3-methylene-4-vinyldihydrofuran-2(3H)-one ligand; η2-η4-complexes of this ligand have been characterised, the latter by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39750000487
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 487-489

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Ring opening of 2,3-bis(hydroxymethyl)methylenecyclopropanes with [Fe2(CO)9]; the molecular structure of a 1,4-diene complex of iron(0), tricarbonyl-η4-(3-methylene-4-vinyldiphydrofuran-2(3H)-one) iron

M. Green, R. P. Hughes and A. J. Welch, J. Chem. Soc., Chem. Commun., 1975, 487 DOI: 10.1039/C39750000487

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