Issue 11, 1975

Formation of CrO22+ in the oxidation of chromium(II) by molecular oxygen

Abstract

Cr2+ reacts with molecular oxygen with a rate constant of (1·6 ± 0·2)× 108l mol–1 s–1 to give a complex, CrO22+, with λmax 245 and 290 nm, ε= 7800 and 3200 l mol–1 cm–1, and which is long lived when [Cr2+][double less-than, compressed][O2].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 401-402

Formation of CrO22+ in the oxidation of chromium(II) by molecular oxygen

R. M. Sellers and M. G. Simic, J. Chem. Soc., Chem. Commun., 1975, 401 DOI: 10.1039/C39750000401

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