Bromination and hydride transfer-carboxylation of 4-homoisotwistane (tricyclo[5,3,1,03,8]undecane)(I) to give the 3-substituted derivatives (II) and (III) as well as ready hydrolysis of the 3-bromide (II) shows the high reactivity of the 3-bridgehead in the hydrocarbon (I).
N. Takaishi, Y. Fujikura, Y. Inamoto, H. Ikeda, K. Aigami and E. Ōsawa, J. Chem. Soc., Chem. Commun., 1975, 371 DOI: 10.1039/C39750000371
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