Steroidal palladium π-allyl complexes are oxidised regiospecifically and with high stereoselectivity to allylic alcohols by 3-chloroperbenzoic acid in light petroleum containing pyridine, the hydroxy-group being delivered preferentially to the same diastereotopic face of the π-allyl system as that originally occupied by palladium.
D. N. Jones and S. D. Knox, J. Chem. Soc., Chem. Commun., 1975, 166 DOI: 10.1039/C39750000166
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