Issue 3, 1975

Acid-catalysed isomerisations of 5,6,7,8-tetrachloro-3,4-dihydro-1,4-dimethyl-1,4- ethenonaphthalen-2(1H)-one (1,4-dimethyltetrachlorobenzobarrelenone)

Abstract

The rearrangement of the title compound (2) in fluorosulphonic acid or sulphuric acid (98%) affords the ketone (6) in good yield whereas the ketones (2) and (6) both give rise to mixtures of the isomers (5) and (9) in sulphuric acid (90%).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 83-84

Acid-catalysed isomerisations of 5,6,7,8-tetrachloro-3,4-dihydro-1,4-dimethyl-1,4- ethenonaphthalen-2(1H)-one (1,4-dimethyltetrachlorobenzobarrelenone)

N. J. Hales and H. Heaney, J. Chem. Soc., Chem. Commun., 1975, 83 DOI: 10.1039/C39750000083

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