Alkyl transfer from mercury to palladium has been shown to proceed with retention of configuration of the alkyl ligand by the reaction of threo and erythro-Me-CH(NMe2)CH(HgCl)Me (I) with bisbenzonitrilepalladium chloride, followed by deuteriation and degradation of the product amines to olefins.
Jan-E. Bäckvall and B. Åkermark, J. Chem. Soc., Chem. Commun., 1975, 82 DOI: 10.1039/C39750000082
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