Sulpholan has been studied by the wide line n.m.r. method over the temperature range 77 to 310 K. Two transitions were observed. The transition centred at 210 K is probably due to molecular reorientation about the two-fold axis, and the transition at 288 K is due to both isotropic rotation and self diffusion. The higher temperature transition shows a hysteresis effect.
D. F. R. Gilson and P. P. Saviotti, J. Chem. Soc., Faraday Trans. 2, 1974, 70, 1 DOI: 10.1039/F29747000001
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