Tin-119 Mössbauer spectra of organotin oxines in applied magnetic fields

Abstract

Signs of the ¹¹⁹Sn quadrupole coupling constants and magnitudes of the asymmetry parameters for several mono-, di-, and tri-organotin oxines and two organotin Schiff base complexes have been determined from magnetically perturbed Mössbauer spectra. These results are used to deduce the probable structures of the compounds. Two of the triphenyltin derivatives are shown to be examples of less common structural types.