Issue 24, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

A possible carbon dioxide complex of molybdenum and its rearrangement product di-µ-carbonato-bis{carbonyltris(dimethylphenylphosphine)molybdenum}: X-ray crystal structure

Joseph Chatt,   Mitsoru Kubota,   G. Jeffery Leigh,   Frank C. March,   Ronald Mason  and  Douglas J. Yarrow  

Abstract

Carbon dioxide reacts with cis-[Mo(N2)2(PMe2Ph)4] to form a complex [Mo(CO2)2(PMe2Ph)4] which changes spontaneously in solution into a carbonato-bridged complex, [(PMe2Ph)3(CO)Mo(CO3)2Mo(CO)(PMe2Ph)3], the structure of which has been determined; the planar carbonate ions bridge in an unusual manner, each being bidentate to one molybdenum atom and monodentate to the other.

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Article information

DOI
https://doi.org/10.1039/C39740001033
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 1033-1034

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A possible carbon dioxide complex of molybdenum and its rearrangement product di-µ-carbonato-bis{carbonyltris(dimethylphenylphosphine)molybdenum}: X-ray crystal structure

J. Chatt, M. Kubota, G. J. Leigh, F. C. March, R. Mason and D. J. Yarrow, J. Chem. Soc., Chem. Commun., 1974, 1033 DOI: 10.1039/C39740001033

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