Perfluoroindene (I), when irradiated in the vapour phase, isomerizes via a sigmatropic fluorine shift to perfluoroisoindene which can be trapped as its Diels–Alder adduct with ethylene; the thermal reaction between (I) and ethylene gives the 1,2-adduct.
W. J. Feast and W. E. Preston, J. Chem. Soc., Chem. Commun., 1974, 985 DOI: 10.1039/C39740000985
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