Large normal (kH/kD > 1) secondary deuterium kinetic isotope effects have been observed in E1 and E2 reactions of some steroidal axial trimethylammonium salts when the leaving groups were partly or fully deuteriated; analogous but much smaller effects have been observed in E2 reactions of 2-phenylethyltrimethyl-ammonium salts.
G. H. Cooper, J. S. Bartlett, A. M. Farid, S. Jones, D. J. Mabbott, J. McKenna, J. M. McKenna and D. G. Orchard, J. Chem. Soc., Chem. Commun., 1974, 950 DOI: 10.1039/C39740000950
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