During a study, which showed that thermal hydrogen atoms generated on a tungsten filament do not in fact react rapidly with solid propene at 77 K, it was found that unexpectedly large i.r. heating effects may occur in refrigerated organic solids in vacuo.
A. K. E. Hagopian and R. H. A. Johnsen, J. Chem. Soc., Chem. Commun., 1974, 837 DOI: 10.1039/C39740000837
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