Evidence is presented that the γ-hydrogen transfer in the decomposition processes of aliphatic aldehydes referred to as McLafferty rearrangement occurs as a discrete step at times longer than ca. 20ps following field ionisation.
R. P. Morgan and P. J. Derrick, J. Chem. Soc., Chem. Commun., 1974, 836 DOI: 10.1039/C39740000836
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