The chloroplatinum(II) chlorovinyl compounds trans-PtCl[CCl![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C(H)R1](PMe2Ph)2, (R1= Me and Ph), react with alcohols R2OH to give alkoxycarbene complexes trans-{PtCl[C(OR2)CH2R1](PMe2Ph)2}+Cl–, (R2= Me, Et, and Prn), which may be isolated as stable hexafluorophosphate salts by the addition of AgPF6.
R. A. Bell and M. H. Chisholm, J. Chem. Soc., Chem. Commun., 1974, 818 DOI: 10.1039/C39740000818
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