trans-Chlorodinitrogenbis(triphenylphosphine) iridium(I) undergoes an oxidative addition reaction with methyl trifluoromethane-sulphonate to give a new dinitrogen complex of iridium(III) with a very high ν(N ![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
N) stretching frequency.
D. M. Blake, J. Chem. Soc., Chem. Commun., 1974, 815 DOI: 10.1039/C39740000815
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