Photoelectron spectroscopic and INDO calculation studies on the 1,3-diaza-adamantan-6-one system are reported; the results clearly indicate through-σ-bond interactions between the nitrogen lone pairs and the carbonyl π-system.
T. Sasaki, S. Eguchi, T. Kiriyama, Y. Sakito and H. Kato, J. Chem. Soc., Chem. Commun., 1974, 725 DOI: 10.1039/C39740000725
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