Spin delocalisation to a dithiocarbamate ligand, and consequent antiferromagnetic interaction, occurs in the d5(t32ge2g) complex but not in the isomorphous d3(t32g) complex; when these interactions are removed by dilution, a sextet–quartet equilibrium is apparent in the d5 complex.
E. J. Cukauskas, B. S. Deaver and E. Sinn, J. Chem. Soc., Chem. Commun., 1974, 698 DOI: 10.1039/C39740000698
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