The decomposition of the 3H-1,2-benzodiazepine (1) is accompanied by its faster equilbration with the isomeric 3H-indazole (4)via a 1,3-shif of the azo group; the establishment of equilibrium and the decomposition have been monitored by high-speed liquid chromatography (h.s.l.c.).
J. N. Done, J. H. Knox, R. McEwan and J. T. Sharp, J. Chem. Soc., Chem. Commun., 1974, 532 DOI: 10.1039/C39740000532
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