Issue 13, 1974

The kinetics of selective solvation of the electron in a binary liquid system

Abstract

Electrons formed by pulse-radiolysis at 107 K in 2-methyltetrahydrofuran (MTHF) containing 0·3 mole-fraction ethanol are first solvated by MTHF molecules which are then all displaced by ethanol molecules in a diffusion-controlled bimolecular process; the resultant ealc species then either decompose unimolecularly or react bimolecularly with a positively charged entity.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 493-494

The kinetics of selective solvation of the electron in a binary liquid system

F. S. Dainton and R. J. Whewell, J. Chem. Soc., Chem. Commun., 1974, 493 DOI: 10.1039/C39740000493

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