Reaction of 2,4-dinitrobenzenediazonium ions with thiophens. An acidic Gomberg reaction
Abstract
2,4-Dinitrobenzenediazonium ions react with thiophen and both methylthiophens in acidic media to yield the corresponding dinitrophenylthiophens; under similar reaction conditions benene was recovered unchanged, while anisole and the diazonium salt couple to give the corresponding azo-dye; thianaphthen also arylates but 2- and 3-methylthianaphthen couple to give azo-dyes.
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