2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.
M. N. Akhtar, W. R. Jackson, J. J. Rooney and N. G. Samman, J. Chem. Soc., Chem. Commun., 1974, 155 DOI: 10.1039/C39740000155
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