Issue 3, 1974

Circular dichroism evidence for a stereospecific complexation reaction in copper(II) chelates of poly-α-amino-acid ligands

Abstract

Evidence is presented for the stereospecific formation of the CuII derivatives of NN′-bis(salicylaldiminato) poly-L-ornithine and poly-L-lysine where the two diastereotopic faces of the square planar metal chelates are alternately bridged to the α-helical polypeptide matrix.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 86-87

Circular dichroism evidence for a stereospecific complexation reaction in copper(II) chelates of poly-α-amino-acid ligands

M. Dentini, P. De Santis and M. Savino, J. Chem. Soc., Chem. Commun., 1974, 86 DOI: 10.1039/C39740000086

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