Issue 2, 1974

Electrophilic substitution by a phenonium ion derived from 1-chloro-2,3-dimethylbenzene: arylation of mesitylene and formation of a biphenyl

Abstract

Reaction of 1-chloro-2,3-dimethylbenzene with nitric acid in acetic anhydride gives 3-chloro-4,5-dimethyl-4-nitro-1,4-dihydrophenyl acetate; the adduct reacts with mesitylene in the presence of trifluoroacetic acid to form 3′-chloro-2,4,4′,5′,6-pentamethylbiphenyl.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 50-51

Electrophilic substitution by a phenonium ion derived from 1-chloro-2,3-dimethylbenzene: arylation of mesitylene and formation of a biphenyl

A. Fischer and C. C. Greig, J. Chem. Soc., Chem. Commun., 1974, 50 DOI: 10.1039/C39740000050

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