The first example of solid linkage isomers containing N- and O-bonded cyanate groups is reported with the compounds Rh(PPh3)3NCO and Rh(PPh3)3OCN; the i.r. spectra of the isomers are discussed, and the solvent-dependence of the mode of co-ordination is noted.
S. J. Anderson, A. H. Norbury and J. Songstad, J. Chem. Soc., Chem. Commun., 1974, 37 DOI: 10.1039/C39740000037
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