Issue 0, 1973

Synthetic studies on terpenoids. Part XVII. Synthetic approaches to hirsutic acid

Abstract

Stereoselective syntheses of some potential intermediates for hirsutic acid (6β,6aβ-epoxy-2,3,3aα,3b,4,5,6,6a,7,7aα-decahydro-5β-hydroxy-2β.3bβ-dimethyl-4-methylene-1H-cyclopenta[a]pentalene-2-carboxylic acid)(I), viz. methyl 3-methyl-6-oxo-cis-bicyclo[3.3.0]octane-3-carboxylate (XVa and b), methyl 1,2,3,3aα,8,8aα-hexahydro-6-methoxy-2β-methylcyclopent[a]indene-2-carboxylate (XXV), and methyl 1,2,3,3aα,8,8aα-hexahydro-6-methoxy-2β-methoxycarbonylmethylcyclopent[a]indene-2-carboxylate (XXIX) are reported.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 2454-2460

Synthetic studies on terpenoids. Part XVII. Synthetic approaches to hirsutic acid

T. K. Sarkar, J. Chem. Soc., Perkin Trans. 1, 1973, 2454 DOI: 10.1039/P19730002454

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements