In the solvolysis of 14β-bromocodeine (1), an important contribution by the hydroxy-group at C-6 has been assumed. In order to investigate this assumption further solvolytic reactions were carried out on several compounds obtained by changing the functional group at C-6 and correlating the products and the reactivity with the different substituents.
K. Abe, M. Onda and S. Okuda, J. Chem. Soc., Perkin Trans. 1, 1973, 316 DOI: 10.1039/P19730000316
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