The paper surveys some recent work on reactions of high temperature species with ordinary compounds on a liquid-nitrogen-cooled surface. Useful syntheses with metal vapours, metal salt vapours, and low-valency boron and silicon compounds, are described. Some reactions which failed are also reported and the reasons for unpredictability in the low-temperature reactions are discussed.
P. L. Timms, Faraday Symp. Chem. Soc., 1973, 8, 68 DOI: 10.1039/FS9730800068
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